Under conditions other than standard state the followingequa

Under conditions other than standard state, the followingequation applies:

Substance Pressure
(\"\)
\"\ 5.55
\"\ 5.75
\"\ 2.25×102

Solution

     G = -2.303 RT logKp
      The given equation is :
        
        Kp = PC2H6 / PH22 PC2H2
               = 2.25 x 10-2 /   5.55 x ( 5.75 )2
                 = 1.226 x 10-4
      We Know that :
         G =   R T ln Kp
                 =   8.314 J / mol- K/ 1000 x 373 K x log (1.226 x 10-4 )
                  
                  = -27.93051 KJ
      
         Grxn. = G0 + RT lnKp                             
                       = -242.1 Kj + ( -27.93051 ) KJ
                        = -270.03KJ                    
        Kp = PC2H6 / PH22 PC2H2
               = 2.25 x 10-2 /   5.55 x ( 5.75 )2
                 = 1.226 x 10-4
      We Know that :
         G =   R T ln Kp
                 =   8.314 J / mol- K/ 1000 x 373 K x log (1.226 x 10-4 )
                  
                  = -27.93051 KJ
      
         Grxn. = G0 + RT lnKp                             
                       = -242.1 Kj + ( -27.93051 ) KJ
                        = -270.03KJ                    
      We Know that :
         G =   R T ln Kp
                 =   8.314 J / mol- K/ 1000 x 373 K x log (1.226 x 10-4 )
                  
                  = -27.93051 KJ
      
         Grxn. = G0 + RT lnKp                             
                       = -242.1 Kj + ( -27.93051 ) KJ
                        = -270.03KJ                    

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